Chemistry › Section L · Kinetics › Topic L.3

Rate laws

Concentration speeds most reactions up, but by how much depends on the reaction. A rate law states the exact relationship, and it can only be found by experiment, usually by comparing initial rates.

In this topic

  • From factors to an equation
  • The form of a rate law
  • Orders come from experiment
  • What each order means
  • The method of initial rates
  • Worked example: the persulfate and iodide reaction
  • Worked example: a ratio that is not a doubling
  • Units of the rate constant
  • Common mistakes to avoid
  • Key takeaways

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