Chemistry › Section L · Kinetics › Topic L.4

Integrated rate laws and half-life

A rate law gives the rate at a given concentration, but often the real question is about time: how much will be left after an hour, or how long until 90% has reacted? Integrated rate laws answer that directly, and the half-life gives a quick feel for a reaction's speed.

In this topic

  • From rates to concentrations over time
  • First-order reactions
  • Worked example: a first-order isomerisation
  • Half-life of a first-order reaction
  • Zero-order and second-order reactions
  • Worked example: a second-order reaction
  • Finding the order from a graph
  • Worked example: which order fits?
  • Common mistakes to avoid
  • Key takeaways

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