Chemistry › Section L · Kinetics › Topic L.6

Reaction mechanisms

A balanced equation shows where a reaction starts and finishes, not how it gets there. A mechanism is the proposed sequence of simple steps along the way, and the rate law is the main evidence for deciding which sequence is right.

In this topic

  • The equation is only a summary
  • Elementary steps and molecularity
  • Rate laws of elementary steps
  • Intermediates and catalysts
  • The rate-determining step
  • Worked example: a slow first step
  • A fast equilibrium before the slow step
  • Worked example: hydrogen and iodine
  • Judging a proposed mechanism
  • Common mistakes to avoid
  • Key takeaways

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