Chemistry › Section F · Electronic structure and periodic properties › Topic F.3

Quantum theory and orbitals

Bohr's orbits explained hydrogen but nothing heavier. The theory that replaced them treats the electron as a wave, describes where it is likely to be rather than where it is, and labels each electron with four quantum numbers that organise the whole of chemistry.

In this topic

  • Beyond Bohr's orbits
  • Matter waves
  • Worked example: an electron and a tennis ball
  • The uncertainty principle
  • Wavefunctions and orbitals
  • Quantum numbers n and l
  • Orientation, shapes and nodes
  • Spin and the Pauli principle
  • Worked example: the n = 3 shell
  • Worked example: allowed sets of quantum numbers
  • Common mistakes to avoid
  • Key takeaways

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