Chemistry › Section E · Thermochemistry › Topic E.3

Enthalpy and Hess's law

Most reactions happen in open containers at constant pressure, and the heat they exchange there has its own name: the enthalpy change, ΔH. Because enthalpy depends only on where a reaction starts and ends, you can add known reactions together to find the ΔH of reactions nobody can measure directly.

In this topic

  • Internal energy and the first law
  • State functions
  • Enthalpy: heat at constant pressure
  • Thermochemical equations
  • Standard enthalpies of combustion and formation
  • Worked example: burning methane
  • Hess's law
  • Worked example: Hess's law in sulfuric acid manufacture
  • Enthalpies of reaction from formation values
  • Worked example: the thermite reaction
  • Common mistakes to avoid
  • Key takeaways

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